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Enhancing thermal-stability of metal electrodes with a sputtered gadolinia-doped ceria over-layer for low-temperature solid oxide fuel cells

Authors
Oh, SeongkookHong, SoonwookKim, Hyong JuneKim, Young-BeomAn, Jihwan
Issue Date
May-2017
Publisher
ELSEVIER SCI LTD
Keywords
Solid oxide fuel cell; Thermal stability; Metal electrode; Oxide over-layer
Citation
CERAMICS INTERNATIONAL, v.43, no.7, pp.5781 - 5788
Indexed
SCIE
SCOPUS
Journal Title
CERAMICS INTERNATIONAL
Volume
43
Number
7
Start Page
5781
End Page
5788
URI
https://scholarworks.bwise.kr/hanyang/handle/2021.sw.hanyang/20342
DOI
10.1016/j.ceramint.2017.01.125
ISSN
0272-8842
Abstract
Cathodic activation loss is the dominant loss mechanism in the operation of low-temperature solid oxide fuel cells (LT-SOFCs). The thermal degradation of metallic cathodes decreases the performance of LT-SOFCs, causing practical issues in long-term operation. In this paper, we investigate the effect of the sputtered gadolinia-doped ceria (GDC) over-layer on the thermal stability of platinum (Pt) cathodes. The thermal stability of Pt cathodes with 23 nm-thick GDC over-layers significantly increased compared to that of the Pt-only cathodes after 2hrs' operation at 450 °C. (< 4% vs. 17% performance degradation, respectively).
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