Synthetic strategy for thienothiophene-benzotriazole-based polymers with high backbone planarity and solubility for field-effect transistor applications
- Authors
- Jo, Yohan; Oh, Jong Gyu; Kim, Cheulhwan; An, Tae Kyu; Jang, Jaeyoung; Lee, Jihoon
- Issue Date
- Jun-2020
- Publisher
- ELSEVIER SCIENCE INC
- Keywords
- Organic field-effect transistor (OFET); Siloxane-terminated side chain; Thienothiophene; Benzotriazole; Conformational locking; Solubility
- Citation
- JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY, v.86, pp.150 - 157
- Indexed
- SCIE
SCOPUS
KCI
- Journal Title
- JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY
- Volume
- 86
- Start Page
- 150
- End Page
- 157
- URI
- https://scholarworks.bwise.kr/hanyang/handle/2021.sw.hanyang/2055
- DOI
- 10.1016/j.jiec.2020.02.022
- ISSN
- 1226-086X
- Abstract
- We report on a synthetic strategy for a series of thienothiophene-benzotriazole-based polymers—octyl-PTTBTz-F, Si-PTTBTz, and Si-PTTBTz-F—wherein conformational locks are introduced to induce intra- and intermolecular interactions (F···S, F···H–C, and C–F···πF) for high backbone planarity and siloxane-terminated side chains are introduced to increase solubility. The three polymers were utilized as active layers in organic field-effect transistors, and the effects of thermal annealing on the polymer crystallinity and device performances were studied. Although the fluorine-atom-substituted octyl-PTTBTz-F showed a moderate hole mobility of up to 4.2 × 10−3 cm2 V−1 s−1 with enhanced molecular orientation because of conformational locks, it had poor solubility in common organic solvents. The Si-PTTBTz polymer with the siloxane-terminated side chains showed good solubility but inferior device performance with a hole mobility of up to 2.2 × 10−4 cm2 V−1 s−1. The rationally designed Si-PTTBTz-F polymer, which contains both fluorine atoms in the backbone and siloxane-terminated groups in the side chains, showed an excellent hole mobility of up to 0.11 cm2 V−1 s−1 and good solubility in common organic solvents.
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