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On-water accelerated sulfenylation of indole derivatives under visible light irradiation

Authors
Lee, Jun SupLee, ChulyongJang, JiwonShin, Seunghoon
Issue Date
Apr-2025
Publisher
Royal Society of Chemistry
Citation
Organic and Biomolecular Chemistry, v.23, no.14, pp 3325 - 3329
Pages
5
Indexed
SCIE
SCOPUS
Journal Title
Organic and Biomolecular Chemistry
Volume
23
Number
14
Start Page
3325
End Page
3329
URI
https://scholarworks.bwise.kr/hanyang/handle/2021.sw.hanyang/206953
DOI
10.1039/d5ob00429b
ISSN
1477-0520
1477-0539
Abstract
A visible-light promoted sulfenylation of N-carboxyindoles with thiols showed substantially higher rate and selectivity when conducted "on water". An EDA complex was proposed to form at the water-oil interface, generating thiyl radicals and thus initiating a chain reaction.
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