Selenized Binary Transition Metals-MXene Composite for High-Performance Asymmetric Hybrid Capacitors

Abstract

The exploration of innovative and high-efficiency energy storage materials is crucial for advancing high-performance supercapacitors. In this study, a novel composite material is synthesized, comprising multilayered MXene (Ti3C2Tx) nanoparticles integrated with porous NiCo2Se4 nanosheets. The accordion-like nanostructure of MXene and its strong interfacial interactions enhance the surface area and cycling stability of the nanocomposite. Additionally, substituting selenium (Se) for Ni-Co-based hydroxides modulates orbital hybridization with the corresponding metal cations, significantly improving electrochemical activity and reducing the adsorption/desorption energy barrier for electrolyte ions. The synergistic interaction between these two materials enabled the composite electrode to achieve a high specific capacity of 796.25 C g(-1) at 1 A g(-1) while maintaining over 90% of its initial capacity after 8000 cycles. Furthermore, the as-fabricated asymmetric hybrid capacitor, employing activated carbon as the negative electrode, delivered an energy density of 64.36 Wh kg(-1) at a power density of 0.8 kW kg(-1), surpassing the performance of most previously reported hybrid capacitors. The developed composite structure holds significant potential for integration into various electrochemical devices, such as batteries, sensors, and electrolyzers.