Output performance of zinc tin oxide nanoparticle-based piezoelectric nanogenerators with different shapes and phases

Abstract

This study reports the characteristics of a piezoelectric nanogenerator (PENG) consisting of a mixture of polydimethylsiloxane (PDMS) and zinc tin oxide (ZTO) particles (ZTO@PDMS) with different shapes and phases. The output performance of PENGs with crystalline Zinc hydroxystannate(ZHS), amorphous ZTO, and crystalline ZTO of different phases was investigated based on annealing temperature. The fabricated PENGs with amorphous ZTO (a-ZTO) cubes showed a maximum output voltage of ∼4.3V and a current of ∼470 nA with a power of 3.14 μW, which is 249 % higher than that of the crystalline ZTO (c-ZTO) cube-based one. The amorphous ZTO (a-ZTO) nanosphere showed the highest output performance. The surface area of the piezoelectric material affected the residual polarization, which led to different piezoelectric properties. Therefore, we investigated the output performance of PENGs with various shapes while maintaining the same volumes of ZTO cubes and spheres. The molar ratio of the materials was varied during synthesis, revealing that the ZTO cubes have a higher output performance. The polarization-electric loops (P-E loops) showed a high remnant polarization (Pr∼25.89μC/cm2) in ZTO@PDMS films with larger 1103 nm cubes. These values were 170.5 %, 143.7 %, and 113.2 % larger than those observed in ZTO@PDMS films with cubes of size 826 nm, 978 nm, and 1047 nm, respectively. The ZTO nanocubes have a significant advantage in the fabrication of high output performance based on PENGs.