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The effect of Zn coating layers on the hydrogen embrittlement of hot-dip galvanized twinning-induced plasticity steel

Authors
Jeon, Hyun-HeeLee, Sang-MinHan, Jeong hoPark, Ii-JeongLee, Young-Kook
Issue Date
Oct-2016
Publisher
PERGAMON-ELSEVIER SCIENCE LTD
Keywords
Intermetallics; Metal coatings; Steel; Zinc; Hydrogen embrittlement
Citation
CORROSION SCIENCE, v.111, pp.267 - 274
Indexed
SCIE
SCOPUS
Journal Title
CORROSION SCIENCE
Volume
111
Start Page
267
End Page
274
URI
https://scholarworks.bwise.kr/hanyang/handle/2021.sw.hanyang/22096
DOI
10.1016/j.corsci.2016.05.014
ISSN
0010-938X
Abstract
The effect of Zn coating layers on hydrogen embrittlement (HE) was investigated using hot-dip galvanized (HDG) twinning-induced plasticity (TWIP) steel. The Zn coating layers consisted of an eta-Zn layer and Fe-Zn intermetallic layers of zeta and delta without Gamma. H was trapped particularly at the zeta layer without Zn-H compounds. The activation energies of H desorption from the delta and zeta layers were 60.0 kJ mol(-1) and 75.4kJmol(-1), respectively. The H-charged HDG_TWIP steel did not reveal HE due to the intermetallic layers, which are exceptionally brittle even when H is not enriched.
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