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Effect of conformation on the properties of uniaxially drawn polylacide films upon drawing temperature

Authors
Oh, Mi OkKim, Seong Hun
Issue Date
Jul-2016
Publisher
KOREAN FIBER SOC
Keywords
Poly(lactide); alpha ' phase; Uniaxial drawing; Strain induced crystalline; Molecular orientation
Citation
FIBERS AND POLYMERS, v.17, no.7, pp.992 - 999
Indexed
SCIE
SCOPUS
KCI
Journal Title
FIBERS AND POLYMERS
Volume
17
Number
7
Start Page
992
End Page
999
URI
https://scholarworks.bwise.kr/hanyang/handle/2021.sw.hanyang/22324
DOI
10.1007/s12221-016-6048-0
ISSN
1229-9197
Abstract
Polylactide(PLA) films were drawn at various drawing temperature of 65, 90 and 120 A degrees C. The effects of drawing temperature on structural conformation and properties of PLA films were investigated. It was confirmed that the PLA films at drawing temperature of 65 and 90 A degrees C were composed of alpha' phase crystal form. The strain-induced crystallization and molecular orientation increased with increasing the draw ratio, which result in improving the mechanical and thermal properties of alpha' phase PLA films. However, at drawing temperature of 120 A degrees C, the strain-induced crystallization and molecular orientation of PLA films were not distinctly detected. It was supposed that the rate of the chain relaxation was faster than chain orientation and strain-induced crystallization during uniaxial drawing process.
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