Effectively suppressing dissolution of manganese from spinel lithium manganate via a nanoscale surface-doping approachopen access
- Authors
- Lu, Jun; Zhan, Chun; Wu, Tianpin; Wen, Jianguo; Lei, Yu; Kropf, A. Jeremy; Wu, Huiming; Miller, Dean J.; Elam, Jeffrey W.; Sun, Yang Kook; Qiu, Xinping; Amine, Khalil
- Issue Date
- Dec-2014
- Publisher
- NATURE PUBLISHING GROUP
- Citation
- NATURE COMMUNICATIONS, v.5
- Indexed
- SCIE
SCOPUS
- Journal Title
- NATURE COMMUNICATIONS
- Volume
- 5
- URI
- https://scholarworks.bwise.kr/hanyang/handle/2021.sw.hanyang/25699
- DOI
- 10.1038/ncomms6693
- ISSN
- 2041-1723
- Abstract
- The capacity fade of lithium manganate-based cells is associated with the dissolution of Mn from cathode/electrolyte interface due to the disproportionation reaction of Mn( III), and the subsequent deposition of Mn(II) on the anode. Suppressing the dissolution of Mn from the cathode is critical to reducing capacity fade of LiMn2O4-based cells. Here we report a nanoscale surface-doping approach that minimizes Mn dissolution from lithium manganate. This approach exploits advantages of both bulk doping and surface-coating methods by stabilizing surface crystal structure of lithium manganate through cationic doping while maintaining bulk lithium manganate structure, and protecting bulk lithium manganate from electrolyte corrosion while maintaining ion and charge transport channels on the surface through the electrochemically active doping layer. Consequently, the surface-doped lithium manganate demonstrates enhanced electrochemical performance. This study provides encouraging evidence that surface doping could be a promising alternative to improve the cycling performance of lithium-ion batteries.
- Files in This Item
-
Go to Link
- Appears in
Collections - 서울 공과대학 > 서울 에너지공학과 > 1. Journal Articles
![qrcode](https://api.qrserver.com/v1/create-qr-code/?size=55x55&data=https://scholarworks.bwise.kr/hanyang/handle/2021.sw.hanyang/25699)
Items in ScholarWorks are protected by copyright, with all rights reserved, unless otherwise indicated.