An overview of different strategies to introduce conductivity in metal-organic frameworks and miscellaneous applications thereof
- Authors
- Bhardwaj, Sanjeev K.; Bhardwaj, Neha; Kaur, Rajnish; Mehta, Jyotsana; Sharma, Amit L.; Kim, Ki-Hyun; Deep, Akash
- Issue Date
- Aug-2018
- Publisher
- ROYAL SOC CHEMISTRY
- Citation
- JOURNAL OF MATERIALS CHEMISTRY A, v.6, no.31, pp.14992 - 15009
- Indexed
- SCIE
SCOPUS
- Journal Title
- JOURNAL OF MATERIALS CHEMISTRY A
- Volume
- 6
- Number
- 31
- Start Page
- 14992
- End Page
- 15009
- URI
- https://scholarworks.bwise.kr/hanyang/handle/2021.sw.hanyang/3073
- DOI
- 10.1039/c8ta04220a
- ISSN
- 2050-7488
- Abstract
- Metal-organic frameworks (MOFs) are known to possess many interesting material properties such as high specific surface area, tailorable porosity, adsorption/absorption capabilities, post-synthetic modifications, and chemical/thermal stabilities. Because of these unique features, they have been explored for the development of sensors for a variety of analytes. A large proportion of pre-existing MOF-based sensors are well suited for optical transductions due to a lack of electrical conduction in their pristine forms. Hence, the development of MOF-based electrochemical/electrical sensors requires specialized strategies through which MOFs are modified or hybridized with enhanced conductive moieties (e.g., via doping or post synthetic modification). In this review article, we provide a comprehensive review of various synthetic and integrating strategies to improve electrical conductivity and long-range charge transport properties in MOFs. To this end, we have compiled details of different techniques that have been used to develop electrically/electrochemically active platforms for MOF-based sensing of various targets.
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