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Aqueous rechargeable Zn-ion batteries: an imperishable and high-energy Zn2V2O7 nanowire cathode through intercalation regulation
- Authors
- Sambandam, Balaji; Soundharrajan, Vaiyapuri; Kim, Sungjin; Alfaruqi, Muhammad H.; Jo, Jeonggeun; Kim, Seokhun; Mathew, Vinod; Sun, Yang-kook; Kim, Jaekook
- Issue Date
- Mar-2018
- Publisher
- Royal Society of Chemistry
- Citation
- Journal of Materials Chemistry A, v.6, no.9, pp 3850 - 3856
- Pages
- 7
- Indexed
- SCI
SCIE
SCOPUS
- Journal Title
- Journal of Materials Chemistry A
- Volume
- 6
- Number
- 9
- Start Page
- 3850
- End Page
- 3856
- ISSN
- 2050-7488
2050-7496
- Abstract
- The use of transition-metal vanadium oxides (TMVOs) for the production of safe and low-cost aqueous rechargeable zinc-ion batteries (ARZIBs) has not been fully explored in detail so far. The electrochemistry involved in multistep Zn2+ insertion/de-insertion induced by vanadium reduction/oxidation in layered α-Zn2V2O7 upon cycling has been interpreted. Layered α-Zn2V2O7 exhibits an excellent specific energy of 166 W h kg−1 and a high capacity retention of 85% after 1000 cycles at an ultra-high current drain of 4000 mA g−1.
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Related Researcher
- Sun, Yang Kook
- COLLEGE OF ENGINEERING (DEPARTMENT OF ENERGY ENGINEERING)