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Atomic layer deposition of GDC cathodic functional thin films for oxide ion incorporation enhancement

Authors
Yang, HwichulLee, HojaeLim, YonghyunKim, Young-Beom
Issue Date
Jan-2021
Publisher
WILEY
Keywords
atomic layer deposition; functional interlayer; Gadolinia-doped ceria; low-temperature solid oxide fuel cells; oxide ion incorporation
Citation
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, v.104, no.1, pp.86 - 95
Indexed
SCIE
SCOPUS
Journal Title
JOURNAL OF THE AMERICAN CERAMIC SOCIETY
Volume
104
Number
1
Start Page
86
End Page
95
URI
https://scholarworks.bwise.kr/hanyang/handle/2021.sw.hanyang/8075
DOI
10.1111/jace.17457
ISSN
0002-7820
Abstract
In this paper, we report successful fabrication of a gadolinia-doped ceria (GDC) thin film using atomic layer deposition (ALD) for improving the performance of solid oxide fuel cells (SOFCs). By varying the deposition conditions and adjusting the configuration of the ALD supercycle, the doping ratio of ALD GDC was controlled. The morphology, crystallinity, and chemical composition of ALD GDC thin films were analyzed. ALD GDC showed different surface chemistry, including oxidation states, at different doping ratios. The application of ALD GDC in a SOFC led to an output power density enhancement greater than 2.5 times. With an anodic aluminum oxide (AAO) porous support structure, an ALD GDC thin film SOFC (TF-SOFC) showed a high power density of 288.24 mW/cm(2)at an operating temperature of 450 degrees C.
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