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Phosphorescent Iridium Complexes for OLEDs Based on 1-Phenylpyrazole Ligands with Fluorine and Methyl Moieties

Authors
Yoon, Seung SooSong, Ji YoungNa, Eun JaeLee, Kum HeeKim, Seong KyuLim, Dong WhanLee, Seok JaeKim, Young Kwan
Issue Date
20-May-2013
Publisher
WILEY-V C H VERLAG GMBH
Keywords
Phosphorescence; Iridium complex; Phenylpyrazole ligand; White OLED
Citation
BULLETIN OF THE KOREAN CHEMICAL SOCIETY, v.34, no.5, pp.1366 - 1370
Journal Title
BULLETIN OF THE KOREAN CHEMICAL SOCIETY
Volume
34
Number
5
Start Page
1366
End Page
1370
URI
https://scholarworks.bwise.kr/hongik/handle/2020.sw.hongik/17125
DOI
10.5012/bkcs.2013.34.5.1366
ISSN
0253-2964
Abstract
A series of phosphorescent iridium(III) complexes 1-4 based on phenylpyrazole were synthesized and their photophysical properties were investigated. To evaluate their electroluminescent properties, OLED devices with the structure of ITO/NPB/mCP: 8% Iridium complexes (1-4)/TPBi/Liq/Al were fabricated. Among those, the device with 3 showed the most efficient white emission with maximum luminance of 100.6 cd/m(2) at 15 V, maximum luminous efficiency of 1.52 cd/A, power efficiency of 0.71 lm/W, external quantum efficiency of 0.59%, and CIE coordinates of (0.35, 0.40) at 15.0 V, respectively.
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