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Origin of Low Photocatalytic Activity of Rutile TiO2

Authors
Jung, Hyun SukKim, Hyungtak
Issue Date
Jun-2009
Publisher
KOREAN INST METALS MATERIALS
Keywords
Photocatalyst; Nanoparticle; Rutile; Anatase; Charge recombination
Citation
ELECTRONIC MATERIALS LETTERS, v.5, no.2, pp.73 - 76
Journal Title
ELECTRONIC MATERIALS LETTERS
Volume
5
Number
2
Start Page
73
End Page
76
URI
https://scholarworks.bwise.kr/hongik/handle/2020.sw.hongik/21849
DOI
10.3365/eml.2009.06.073
ISSN
1738-8090
Abstract
Rutile TiO2 nanoparticles were synthesized using the colloidal sol-gel process and their photocatalytic properties were characterized in comparison with anatase TiO2 nanoparticles. The synthesized rutile nanoparticles were found to possess higher surfaces area than the anatase nanoparticles and to exhibit lower photocatalytic activities, demonstrating that rutile TiO2 has intrinsically low photocatalytic properties. The photoluminescence (PL) study suggested that the inferior photocatalytic activity of rutile nanoparticles is correlated with the intrinsic recombination of photogenerated electron-hole pairs.
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