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New heteroleptic iridium complexes having one biphenyl-2,2 '-diyl and two bipyridyl based ligands
- Authors
- Lee, Kyu Reon; Eum, Min-Sik; Chin, Chong Shik; Lee, Seung Chan; Kim, In June; Kim, Young Sik; Kim, Youngmee; Kim, Sung-Jin; Hur, Nam Hwi
- Issue Date
- 2009
- Publisher
- ROYAL SOC CHEMISTRY
- Citation
- DALTON TRANSACTIONS, no.19, pp.3650 - 3652
- Journal Title
- DALTON TRANSACTIONS
- Number
- 19
- Start Page
- 3650
- End Page
- 3652
- ISSN
- 1477-9226
- Abstract
- The structural and spectroscopic properties of new heteroleptic iridium complexes having a biphenyl and two bipyridyl based ligands are reported; DFT calculations reveal that the HOMO is composed of the biphenyl and iridium d orbitals while the LUMO is localized mainly on the two bipyridyl based ligands.
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