The heteroleptic complexes containing 2,3-diphenylquinoline derivatives as phosphorescent materials
- Authors
- Ahn, So Youn; Ko, Myung Joo; Ha, Yunkyoung
- Issue Date
- May-2008
- Publisher
- PERGAMON-ELSEVIER SCIENCE LTD
- Citation
- JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, v.69, no.5-6, pp.1320 - 1324
- Journal Title
- JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS
- Volume
- 69
- Number
- 5-6
- Start Page
- 1320
- End Page
- 1324
- URI
- https://scholarworks.bwise.kr/hongik/handle/2020.sw.hongik/22741
- DOI
- 10.1016/j.jpcs.2007.10.126
- ISSN
- 0022-3697
- Abstract
- New types of heteroleptic iridium complexes were designed and synthesized with two different species of chelating ligands (C boolean AND N) in this study. Ir(ppy)(2)(4-Me-2,3-dpq), Ir(ppy)(4-Me-2,3-dpq)(2), Ir(pq)(2)(4-Me-2,3-dpq) and Ir(pq)(4-Me-2,3-dpq)(2) were prepared, where ppy, 4-Me-2,3-dpq and pq represent 2-phenylpyridine, 4-methyl-2,3-diphenylquinoline and 2-phenylquinoline, respectively. According to our previous study, Ir(4-Me-2,3-dpq)(2)(acac) showed orange-red emission at 603 nm with the luminescence efficiency of 8.10 cd/A in electroluminescence (EL) spectra. On the otherhand, Ir(ppy)(2)(acac), a green phosphor, has been known to have an outstanding efficiency of more than 45 cd/A. In order to improve the luminescence efficiency, it is necessary to design a phosphorescent material which is capable of transferring the excited energy efficiently and properly. The heteroleptic Ir(III) complexes containing two different kinds of ligands can have a high luminescence efficiency by intramolecular energy transfer from the energy-absorbing ligand to the luminescent ligand, leading to a decrease in quenching or energy deactivation. Thus, the luminescence characteristics of the iridium, complexes prepared herein were investigated. Ir(ppy)(2)(4-Me-2,3-dpq), Ir(ppy)(4-Me-2,3-dpq)(2), Ir(pq)(2)(4-Me-2,3-dpq) and Ir(pq)(4-Me-2,3-dpq)(2) exhibited the emission maxima at 512, 512, 583, and 584 nm, respectively. Two different light-emitting mechanisms were suggested to explain these phenomena. (C) 2007 Elsevier Ltd. All rights reserved.
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