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Self-assembly of one-dimensional coordination polymers from AgX (X = CF3SO3-, ClO4-, and NO3-) and 2-aminomethylpyridinedipropionitrile (2-AMPDPN)

Authors
Kang, YJLee, SSPark, KMLee, SHKang, SOKo, JJ
Issue Date
31-Dec-2001
Publisher
AMER CHEMICAL SOC
Citation
INORGANIC CHEMISTRY, v.40, no.27, pp.7027 - 7031
Journal Title
INORGANIC CHEMISTRY
Volume
40
Number
27
Start Page
7027
End Page
7031
URI
https://scholarworks.bwise.kr/hongik/handle/2020.sw.hongik/27164
DOI
10.1021/ic0105765
ISSN
0020-1669
Abstract
Three novel supramolecules whose topologies depend on the counteranion, [Ag(2-AMPDPN)X] (X = CF3SO3- (1), ClO4- (2), and NO3- (3)), have been prepared by the self-assembly of AgX (X = CF3SO3-, ClO4-, and NO3-) with 2-aminomethylpyridinedipropionitrile (2-AMPDPN). The crystal structures reveal different packing arrangements of the one-dirnensional infinite coordination polymers. Compound 1 is made up of ladder chains that Lire interlocked by cyano groups, while the polymeric chain of 2 is isomorphous to 1 except for the Ag-Ag interaction. Compound 3 consists of helical chains that are surrounded by nitrate. The adjacent helical chains are racemic. The structures of 1, 2, and 3 suggest the role that the counterions may play in the network construction.
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