Self-assembly of one-dimensional coordination polymers from AgX (X = CF3SO3-, ClO4-, and NO3-) and 2-aminomethylpyridinedipropionitrile (2-AMPDPN)
- Authors
- Kang, YJ; Lee, SS; Park, KM; Lee, SH; Kang, SO; Ko, JJ
- Issue Date
- 31-Dec-2001
- Publisher
- AMER CHEMICAL SOC
- Citation
- INORGANIC CHEMISTRY, v.40, no.27, pp.7027 - 7031
- Journal Title
- INORGANIC CHEMISTRY
- Volume
- 40
- Number
- 27
- Start Page
- 7027
- End Page
- 7031
- URI
- https://scholarworks.bwise.kr/hongik/handle/2020.sw.hongik/27164
- DOI
- 10.1021/ic0105765
- ISSN
- 0020-1669
- Abstract
- Three novel supramolecules whose topologies depend on the counteranion, [Ag(2-AMPDPN)X] (X = CF3SO3- (1), ClO4- (2), and NO3- (3)), have been prepared by the self-assembly of AgX (X = CF3SO3-, ClO4-, and NO3-) with 2-aminomethylpyridinedipropionitrile (2-AMPDPN). The crystal structures reveal different packing arrangements of the one-dirnensional infinite coordination polymers. Compound 1 is made up of ladder chains that Lire interlocked by cyano groups, while the polymeric chain of 2 is isomorphous to 1 except for the Ag-Ag interaction. Compound 3 consists of helical chains that are surrounded by nitrate. The adjacent helical chains are racemic. The structures of 1, 2, and 3 suggest the role that the counterions may play in the network construction.
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Collections - College of Science and Technology > Department of Biological and Chemical Engineering > 1. Journal Articles
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