Potential energy surface from spectroscopic data in the photodissociation of polyatomic molecules
- Authors
- Kim, HJ; Kim, YS
- Issue Date
- 20-May-2001
- Publisher
- KOREAN CHEMICAL SOC
- Keywords
- potential energy surface; wave packet propagation; inversion method; photodissociation dynamics; Raman spectra
- Citation
- BULLETIN OF THE KOREAN CHEMICAL SOCIETY, v.22, no.5, pp.455 - 462
- Journal Title
- BULLETIN OF THE KOREAN CHEMICAL SOCIETY
- Volume
- 22
- Number
- 5
- Start Page
- 455
- End Page
- 462
- URI
- https://scholarworks.bwise.kr/hongik/handle/2020.sw.hongik/27213
- ISSN
- 0253-2964
- Abstract
- The time-dependent tracking inversion method is studied to extract the potential energy surface of the electronic excited state in the photodissociation of triatomic molecules. Based on the relay of the regularized inversion procedure acid time-dependent wave packet propagation, the algorithm extracts the underlying potential energy surface piece by piece by tracking the time-dependent data. which can be synthesized from Raman excitation profiles. We have demonstrated the algorithm to extract the potential energy surface of electronic excited state for NO(2) molecule where the wave packet split on a saddle-shaped surface. Finally, we describe the merits of the time-dependent tracking inversion method compared with the time-independent inversion method and discussed several extensions of the algorithm.
- Files in This Item
- There are no files associated with this item.
- Appears in
Collections - College of Engineering > Department of Science > 1. Journal Articles
![qrcode](https://api.qrserver.com/v1/create-qr-code/?size=55x55&data=https://scholarworks.bwise.kr/hongik/handle/2020.sw.hongik/27213)
Items in ScholarWorks are protected by copyright, with all rights reserved, unless otherwise indicated.