Characterization of Hall Factor with Seebeck Coefficient Measurement

Abstract

The density-of-states effective mass (md*) is commonly obtained by fitting the equation, S = (8π2kB2/3eh2)md∗T(π/3n)2/3 (S, T, and n are the Seebeck coefficient, temperature, and the carrier concentration, respectively), to n-dependent S measurement. However, n is not a measurable parameter. It needs to be converted from the measured Hall carrier concentration (nH) using the Hall factor (rH = n/nH). The rH of material can be estimated by Single Parabolic Band (SPB) model if the band that contributed to transport is approximated to be parabolic and acoustic phonons dominantly scatter its carriers. However, the measurable nH is often used instead of n when utilizing the above equation due to the complex Fermi integrals involved in the SPB model calculation. Consequently, the md∗ estimated from the above equation while using nH would be inaccurate. We propose the equation rH = 1.17 - [0.216 / {1 + exp((|S|-101) / 67.1)}] as a simple and accurate method to obtain the rH from the measured S to facilitate the conversion from nH to n and eventually increase the accuracy of md∗ estimated from the above equation. © 2022 American Chemical Society.