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E-beam Irradiated Fragmentation of Thio-Alkyne Cobaltcarbonyl Complex in Gas Phase as Alkyne Precursor
- Authors
- 황광진
- Issue Date
- 28-Dec-2016
- Publisher
- 한국광과학회
- Citation
- Rapid Communication in Photoscience, v.제5권, no.2호, pp.16 - 17
- Journal Title
- Rapid Communication in Photoscience
- Volume
- 제5권
- Number
- 2호
- Start Page
- 16
- End Page
- 17
- ISSN
- 2288-4564
- Abstract
- Arylalkyne cobalt complexes 5, 6 were prepared and irradiated with e-beam to study their fragmentation focused in alkyne formation. Thioaryl complex 6 showed facile CO ligand release and generated parent alkyne in 89% relative intensity. Meanwhile, hydroxyaryl complex 5 gave alkyne in 6% relative intensity.
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Related Researcher
- Hwang, Kwang Jin
- Science & Technology (Biological and Chemical Engineering)