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Etching characteristics of high-purity aluminum in hydrochloric acid solutions

Authors
Oh, Han-JunLee, Jong-HoAhn, Hong-JooJeong, YongsooPark, No-JinKim, Seong-SuChi, Choong-Soo
Issue Date
25-Mar-2007
Publisher
ELSEVIER SCIENCE SA
Keywords
etch tunnel; capacitance; impedance spectroscopy; aluminum electrolytic capacitors
Citation
MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING, v.449, pp 348 - 351
Pages
4
Journal Title
MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING
Volume
449
Start Page
348
End Page
351
URI
https://scholarworks.bwise.kr/kumoh/handle/2020.sw.kumoh/22251
DOI
10.1016/j.msea.2006.01.159
ISSN
0921-5093
1873-4936
Abstract
We investigated the effects of additives to the etching solution of I M hydrochloric acid on the electrochemical etching behavior for aluminum electrolytic capacitors, using scanning and transmission electron microscopy, and AC impedance spectroscopy. For the addition of I M sulfuric acid or 5% ethylene glycol to the hydrochloric acid solution, the distribution of etch tunnels was more uniform with high density of etch pits compared with that without addition. The highest specific surface area was obtained from the electrolyte with 5% ethylene glycol additive. The correlation of internal morphologies of etched foils with impedance parameters was interpreted by impedance techniques. (c) 2006 Elsevier B.V. All rights reserved.
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