Palladium-Catalyzed Carbonylation with Mo(CO)(6) for the Synthesis of Benzoylacetonitriles
- Authors
- Pyo, Ayoung; Park, Ahbyeol; Jung, Hyun Min; Lee, Sunwoo
- Issue Date
- Sep-2012
- Publisher
- GEORG THIEME VERLAG KG
- Keywords
- carbonylation; cross-coupling; palladium; arylation; molybdenum
- Citation
- SYNTHESIS-STUTTGART, v.44, no.18, pp 2885 - 2888
- Pages
- 4
- Journal Title
- SYNTHESIS-STUTTGART
- Volume
- 44
- Number
- 18
- Start Page
- 2885
- End Page
- 2888
- URI
- https://scholarworks.bwise.kr/kumoh/handle/2020.sw.kumoh/22377
- DOI
- 10.1055/s-0032-1316760
- ISSN
- 0039-7881
1437-210X
- Abstract
- Benzoylacetonitriles were synthesized by the palladium-catalyzed carbonylation of aryl iodides and trimethylsilylacetonitrile using Mo(CO)(6) as a carbon monoxide source. Pd(PPh3)Cl-2 and CuF2 were employed as the catalyst and activator, respectively. A variety of aryl iodides bearing alkyl, alkoxy, fluoro, chloro, bromo, nitrile, ester, and ketone groups afforded the corresponding benzoylacetonitriles in moderate to good yields.
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Collections - Department of Applied Chemistry > 1. Journal Articles
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