Photocurrent Properties of TiO2 Nanorods Grown on FTO by Hydrothermal Method
- Authors
- Kim, Hyun; Yang, Bee Lyong
- Issue Date
- 2015
- Publisher
- KOREAN CERAMIC SOC
- Keywords
- Titanium dioxide(TiO2) nanorod; Hydrothermal method; FTO facing; Photo-activity
- Citation
- JOURNAL OF THE KOREAN CERAMIC SOCIETY, v.52, no.6, pp 531 - 534
- Pages
- 4
- Journal Title
- JOURNAL OF THE KOREAN CERAMIC SOCIETY
- Volume
- 52
- Number
- 6
- Start Page
- 531
- End Page
- 534
- URI
- https://scholarworks.bwise.kr/kumoh/handle/2020.sw.kumoh/22463
- DOI
- 10.4191/kcers.2015.52.6.531
- ISSN
- 1229-7801
2234-0491
- Abstract
- In this work, we undertake a comparative study of the crystallographic microstructures and photo-catalytic properties of rutile TiO2 nanorods grown on FTO facing up and down by a hydrothermal method. An analysis of the fine structures showed that TiO2 nanorods grown on FTO facing up were mixed with sea urchin and microsphere. These structures induced a vertical orientation of the nanorods on FTO. The saturated photocurrent densities of the TiO2 nanorods grown both up and down were 1.5 mA/cm(2) in the former case, the IPCE was increased to 10% at 300 similar to 350 nm. The onset potential (?flat band potential) of the nanorods grown on FTO facing up is negatively shifted to a value of -0.31 V. This is caused by an increase in the surface state, in this case the number of oxygen vacancies, and by the formation of Ti3+. Therefore, the FTO facing direction is considered as a critical factor during the hydrothermal reaction for TiO2 growth so as to develop an efficient photo-catalytic system.
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