Comparison of the Properties of Poly(lactic acid) Nanocomposites with Various Fillers: Organoclay, Functionalized Graphene, or Organoclay/Functionalized Graphene Complex
- Authors
- Kwon, Kidae; Chang, Jin-Hae
- Issue Date
- Mar-2014
- Publisher
- POLYMER SOC KOREA
- Keywords
- poly(lactic acid); organoclay; functionalized graphene oxide; organoclay/functionalized graphene complex; nanocomposite
- Citation
- POLYMER-KOREA, v.38, no.2, pp 232 - 239
- Pages
- 8
- Journal Title
- POLYMER-KOREA
- Volume
- 38
- Number
- 2
- Start Page
- 232
- End Page
- 239
- URI
- https://scholarworks.bwise.kr/kumoh/handle/2020.sw.kumoh/26938
- DOI
- 10.7317/pk.2014.38.2.232
- ISSN
- 0379-153X
2234-8077
- Abstract
- Poly(lactic acid)(PLA) nanocomposites containing various nanofillers were synthesized using the solution intercalation method. Organically modified bentonite clay (NSF), octadecylamine-graphene oxide (ODA-GO), and an NSE/ODA-GO complex were utilized as nanofillers in the fabrication of PLA hybrid films PLA hybrid films with varying nanofiller contents in the range of 0-10 wt% were examined and compared in terms of their thermomechanical properties, morphologies, and oxygen permeabilities. Transmission electron microscopy (TEM) confirmed that most of the NSF and ODA-GO nanofillers were dispersed homogeneously throughout the PLA matrix on the nanoscale, although some agglomerate NSE/ODA-GO complex particles were also formed. Among the three nanofillers for PLA hybrid films, the NSE/ODA-GO complex showed the best improvement in film thermal stability. In contrast, NSF and ODA-GO exhibited the best improvement in tensile mechanical properties and oxygen barrier properties of the PLA hybrid films, respectively.
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