Structures, electrical, and dielectric properties of PVDF-based nanocomposite films reinforced with neat multi-walled carbon nanotube
- Authors
- Kim, Il-Hwan; Baik, Doo Hyun; Jeong, Young Gyu
- Issue Date
- Sep-2012
- Publisher
- POLYMER SOC KOREA
- Keywords
- poly(vinylidene fluoride); multi-walled carbon nanotube; nanocomposite; dielectric property; electrical property
- Citation
- MACROMOLECULAR RESEARCH, v.20, no.9, pp 920 - 927
- Pages
- 8
- Journal Title
- MACROMOLECULAR RESEARCH
- Volume
- 20
- Number
- 9
- Start Page
- 920
- End Page
- 927
- URI
- https://scholarworks.bwise.kr/kumoh/handle/2020.sw.kumoh/28137
- DOI
- 10.1007/s13233-012-0064-8
- ISSN
- 1598-5032
2092-7673
- Abstract
- We report, herein, on the structures, melting/crystallization, electrical, and dielectric properties of poly (vinylidene fluoride) (PVDF) nanocomposites reinforced with a neat multiwalled carbon nanotube (MWCNT). For our purposes, PVDF/MWCNT nanocomposite films with a wide range of MWCNT contents (0.0-20.0 wt%) are prepared via ultrasonicated solution-mixing and melt-compression methods. It is found that MWCNTs become well dispersed in nanocomposites by wrapping them with PVDF chains. The relative content of beta-phase to alpha-phase crystals of a PVDF matrix is higher for the nanocomposite films with higher MWCNT content; although, the overall crystallinity of the nanocomposites is almost identical, irrespective of the MWCNT content. The electrical conductivity and dielectric permittivity of the nanocomposites as a function of frequency are strongly dependent on the MWCNT content. The electrical percolation threshold of PVDF/MWCNT nanocomposites is formed between 2.0 and 5.0 wt% MWCNT. The neat PVDF and nanocomposites with low MWCNT contents of 0.2 and 1.0 wt% are electrically insulating materials (similar to 10(-9) S/cm at 10(2) Hz) with low dielectric permittivity of 9-28; while the nanocomposites with high MWCNT contents of 5.0-20.0 wt% have relatively high electrical conductivity values (10(-4 similar to)10(-2) S/cm at 10(2) Hz). In contrast, the nanocomposite with 2.0 wt% MWCNT has a huge dielectric permittivity of similar to 6520 at 10(2) Hz, although it has relatively low electrical conductivity of similar to 10(-8) S/cm at 10(2) Hz. The huge dielectric permittivity of the nanocomposite with 2.0 wt% MWCNT could be caused by charge accumulation at the interfacial layers between PVDF chains and MWCNTs in the vicinity of the electrical percolation threshold.
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