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Facile fabrication of novel ceria-based nanocomposite (CYO-CSO) via co-precipitation: Electrochemical, photocatalytic and antibacterial performances

Authors
Kannan, KarthikRadhika, D.Kasai, R. DeepakGnanasangeetha, D.Palani, GeethaGurushankar, K.Koutavarapu, RavindranadhLee, Dong-YeonShim, Jaesool
Issue Date
May-2022
Publisher
ELSEVIER
Keywords
Mixed metal oxide nanocomposite; CYO-CSO; Chemical precipitation; Photocatalytic; Antibacterial
Citation
JOURNAL OF MOLECULAR STRUCTURE, v.1256
Journal Title
JOURNAL OF MOLECULAR STRUCTURE
Volume
1256
URI
https://scholarworks.bwise.kr/kumoh/handle/2020.sw.kumoh/28369
DOI
10.1016/j.molstruc.2022.132519
ISSN
0022-2860
1872-8014
Abstract
Ceria-based mixed metal oxide (rare-earth-based) nanocomposites have become well-known and play an important part in contemporary nanotechnology research due to their superior photocatalytic, bio-logical, and electrochemical performance. A Ce0.8Y0.2 O2-delta-Ce0.8Sm0.2O2-delta (CYO-CSO) nanocomposite was fabricated utilizing a chemical precipitation technique for a variety of applications. For structural study, Fourier transfer infrared (FT-IR) spectroscopy, X-ray powder diffraction (XRD), and thermographic analysis (TGA) were used, as well as Scanning Electronic microscopy (SEM) and Energy dispersive X-ray analysis (EDX) for morphological and elemental analysis. There was no secondary phase seen during the creation of fluorite cubic crystal arrangement. XRD and FTIR were used to reveal the metal-oxygen connection. UV-Vis spectroscopy was used to calculate the optical bandgap of the produced nanocomposite. Elec-trochemical characteristics were discovered when conducting electrochemical impedance studies (EIS) at a frequency range of 40 Hz to 6 kHz and a voltage of 1.3 V. Methylene blue (MB) was utilized to es-timate photocatalytic performance. The photocatalytic performance of CYO-CSO nanocomposite for MB dye was shown to be superior (93%). The antibacterial characteristic features of the synthesized CYO-CSO nanocomposite against foodborne pathogens are satisfactory.(C) 2022 Elsevier B.V. All rights reserved.
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