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Visible-light-induced photocatalytic trifluoromethylation/1,2-carbon migration sequences for the synthesis of CF3-substituted cyclic ketones
- Authors
- Woo, Saet Byeol; Kim, Dae Young
- Issue Date
- Oct-2015
- Publisher
- Elsevier BV
- Keywords
- Trifluoromethylation; Photocatalysis; Radical reaction; 1,2-Carbon migration
- Citation
- Journal of Fluorine Chemistry, v.178, pp 214 - 218
- Pages
- 5
- Journal Title
- Journal of Fluorine Chemistry
- Volume
- 178
- Start Page
- 214
- End Page
- 218
- ISSN
- 0022-1139
1873-3328
- Abstract
- A visible-light-induced photoredox trifluoromethylation/1,2-carbon migration sequence of alkenols is described. This approach provides a mild and operationally simple access to the synthesis of CF3-substituted cyclic ketones via trifluoromethylation and 1,2-carbon migration of 1-(1-arylvinyl)cyclobutanol derivatives. (C) 2015 Elsevier B.V. All rights reserved.
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Related Researcher
- Kim, Dae Young
- College of Natural Sciences (Department of Chemistry)