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Enantioselective fluorination of alpha-chloro-beta-keto phosphonates in the presence of chiral palladium complexes
- Issue Date
- 26-Jun-2013
- Publisher
- Elsevier BV
- Keywords
- Asymmetric catalysis; Chiral palladium catalysts; Electrophilic fluorination; alpha-Chloro-beta-keto phosphonates
- Citation
- Tetrahedron Letters, v.54, no.26, pp 3359 - 3362
- Pages
- 4
- Journal Title
- Tetrahedron Letters
- Volume
- 54
- Number
- 26
- Start Page
- 3359
- End Page
- 3362
- ISSN
- 0040-4039
- Abstract
- The catalytic enantioselective electrophilic fluorination of alpha-chloro-beta-keto phosphonates promoted by chiral palladium complexes has been developed, allowing facile synthesis of the corresponding alpha-chloro-alpha-fluoro-beta-keto phosphonates with excellent enantioselectivity (up to 95% ee). (c) 2013 Elsevier Ltd. All rights reserved.
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Related Researcher
- Kim, Dae Young
- College of Natural Sciences (Department of Chemistry)