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Synthesis and electrochemical characterization of Li11Nb0.9O2-x as a novel active material for the negative electrode of lithium secondary batteries

Authors
Kim, Yang-SooNa, KangmoonLee, Min-HyungBack, ChangkeunBaik, YounkeeJeong, Euh-DuckHwang, Son-HoLee, Sang-RhoYin, Ri-ZhuJeong, Soon-Ki
Issue Date
15-Sep-2012
Publisher
Elsevier BV
Keywords
Lithium secondary battery; Negative electrode; Niobium; Rietveld refinement; Charge and discharge; Cyclic voltammetry; First principles calculation
Citation
Materials Letters, v.83, pp 14 - 16
Pages
3
Journal Title
Materials Letters
Volume
83
Start Page
14
End Page
16
URI
https://scholarworks.bwise.kr/sch/handle/2021.sw.sch/14836
DOI
10.1016/j.matlet.2012.05.102
ISSN
0167-577X
1873-4979
Abstract
An oxide, Li1.1Nb0.9O2 - x, is proposed as a novel active material for the negative electrode of lithium secondary batteries. The material was selected by first principles calculation and its real properties as a negative electrode were measured after it is synthesized by solid state reactions. Lithium ions are inserted into the material at potentials <0.3 V vs. Li/Li+. Its reversible capacity is similar to 120 mAh g(-1) after 50 cycles. (C) 2012 Elsevier B.V. All rights reserved.
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