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Catalytic enantioselective chlorination of cyclic beta-keto esters in the presence of chiral Pd(II) complexes
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| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Kang, Young Ku | - |
| dc.contributor.author | Kim, Hee Hun | - |
| dc.contributor.author | Koh, Kwang Oh | - |
| dc.contributor.author | Kim, Dae Young | - |
| dc.date.accessioned | 2021-08-12T02:47:50Z | - |
| dc.date.available | 2021-08-12T02:47:50Z | - |
| dc.date.issued | 2012-07-18 | - |
| dc.identifier.issn | 0040-4039 | - |
| dc.identifier.uri | https://scholarworks.bwise.kr/sch/handle/2021.sw.sch/14999 | - |
| dc.description.abstract | The catalytic enantioselective electrophilic chlorination promoted by chiral palladium complexes is described. The treatment of beta-keto esters with 2,3,4,5,6,6-hexachlorocyclohex-2,4-dienone as chlorine source under mild reaction conditions afforded the corresponding a-chlorinated beta-keto esters with excellent enantioselectivities (up to 94% ee). (C) 2012 Elsevier Ltd. All rights reserved. | - |
| dc.format.extent | 4 | - |
| dc.language | 영어 | - |
| dc.language.iso | ENG | - |
| dc.publisher | Elsevier BV | - |
| dc.title | Catalytic enantioselective chlorination of cyclic beta-keto esters in the presence of chiral Pd(II) complexes | - |
| dc.type | Article | - |
| dc.publisher.location | 영국 | - |
| dc.identifier.doi | 10.1016/j.tetlet.2012.05.064 | - |
| dc.identifier.scopusid | 2-s2.0-84862160421 | - |
| dc.identifier.wosid | 000306027700031 | - |
| dc.identifier.bibliographicCitation | Tetrahedron Letters, v.53, no.29, pp 3811 - 3814 | - |
| dc.citation.title | Tetrahedron Letters | - |
| dc.citation.volume | 53 | - |
| dc.citation.number | 29 | - |
| dc.citation.startPage | 3811 | - |
| dc.citation.endPage | 3814 | - |
| dc.type.docType | Article | - |
| dc.description.isOpenAccess | N | - |
| dc.description.journalRegisteredClass | sci | - |
| dc.description.journalRegisteredClass | scie | - |
| dc.description.journalRegisteredClass | scopus | - |
| dc.relation.journalResearchArea | Chemistry | - |
| dc.relation.journalWebOfScienceCategory | Chemistry, Organic | - |
| dc.subject.keywordPlus | MANNICH-TYPE REACTIONS | - |
| dc.subject.keywordPlus | ASYMMETRIC ALPHA-CHLORINATION | - |
| dc.subject.keywordPlus | CONJUGATE ADDITION | - |
| dc.subject.keywordPlus | ELECTROPHILIC FLUORINATION | - |
| dc.subject.keywordPlus | CARBONYL-COMPOUNDS | - |
| dc.subject.keywordPlus | ALPHA,BETA-UNSATURATED KETONES | - |
| dc.subject.keywordPlus | CINCHONA ALKALOIDS | - |
| dc.subject.keywordPlus | KETOESTERS | - |
| dc.subject.keywordPlus | PHOSPHONATES | - |
| dc.subject.keywordPlus | AMINATION | - |
| dc.subject.keywordAuthor | Chlorination | - |
| dc.subject.keywordAuthor | Asymmetric catalysis | - |
| dc.subject.keywordAuthor | Chiral palladium catalysts | - |
| dc.subject.keywordAuthor | beta-Keto esters | - |
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Related Researcher
- Kim, Dae Young
- College of Natural Sciences (Department of Chemistry)