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Catalytic enantioselective chlorination of cyclic beta-keto esters in the presence of chiral Pd(II) complexes
- Issue Date
- 18-Jul-2012
- Publisher
- Elsevier BV
- Keywords
- Chlorination; Asymmetric catalysis; Chiral palladium catalysts; beta-Keto esters
- Citation
- Tetrahedron Letters, v.53, no.29, pp 3811 - 3814
- Pages
- 4
- Journal Title
- Tetrahedron Letters
- Volume
- 53
- Number
- 29
- Start Page
- 3811
- End Page
- 3814
- ISSN
- 0040-4039
- Abstract
- The catalytic enantioselective electrophilic chlorination promoted by chiral palladium complexes is described. The treatment of beta-keto esters with 2,3,4,5,6,6-hexachlorocyclohex-2,4-dienone as chlorine source under mild reaction conditions afforded the corresponding a-chlorinated beta-keto esters with excellent enantioselectivities (up to 94% ee). (C) 2012 Elsevier Ltd. All rights reserved.
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Related Researcher
- Kim, Dae Young
- College of Natural Sciences (Department of Chemistry)