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Enantioselective Michael Addition of 3-Aryl-Substituted Oxindoles to Methyl Vinyl Ketone Catalyzed by a Binaphthyl-Modified Bifunctional Organocatalyst
- Authors
- Lee, Hyun Joo; Woo, Saet Byeol; Kim, Dae Young
- Issue Date
- Jun-2012
- Publisher
- Multidisciplinary Digital Publishing Institute (MDPI)
- Keywords
- oxindole; methyl vinyl ketone; conjugate addition; bifunctional organocatalysis; asymmetric catalysis
- Citation
- Molecules, v.17, no.6, pp 7523 - 7532
- Pages
- 10
- Journal Title
- Molecules
- Volume
- 17
- Number
- 6
- Start Page
- 7523
- End Page
- 7532
- ISSN
- 1420-3049
- Abstract
- The enantioselective conjugate addition reaction of 3-aryl-substituted oxindoles with methyl vinyl ketone promoted by binaphthyl-modified bifunctional organocatalysts was investigated. The corresponding Michael adducts, containing a quaternary center at the C3-position of the oxindoles, were generally obtained in high yields with excellent enantioselectivities (up to 91% ee).
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Related Researcher
- Kim, Dae Young
- College of Natural Sciences (Department of Chemistry)