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Chiral Pd-catalyzed enantioselective Friedel-Crafts reaction of indoles with gamma,delta-unsaturated beta-keto phosphonates
- Issue Date
- 22-Jun-2011
- Publisher
- Elsevier BV
- Keywords
- Friedel-Crafts reaction; Asymmetric catalysis; Chiral palladium catalysts; Indoles; gamma,delta-Unsaturated beta-keto phosphonates
- Citation
- Tetrahedron Letters, v.52, no.25, pp 3247 - 3249
- Pages
- 3
- Journal Title
- Tetrahedron Letters
- Volume
- 52
- Number
- 25
- Start Page
- 3247
- End Page
- 3249
- ISSN
- 0040-4039
- Abstract
- The catalytic enantioselective Friedel-Crafts alkylation reaction promoted by chiral palladium complexes is described. The treatment of indoles with gamma,delta-unsaturated beta-keto phosphonates under the mild reaction conditions afforded the corresponding Friedel-Crafts alkylation adducts with excellent enantioselectivities (up to 99% ee). (C) 2011 Elsevier Ltd. All rights reserved.
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Related Researcher
- Kim, Dae Young
- College of Natural Sciences (Department of Chemistry)