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Visible Light Photocatalytic Trifluoromethylation/SET Oxidation/Cycloaddition Sequences of 2-Vinyl Phenols: Multicomponent Synthesis of 4H-Chromenes
- Authors
- Jang, Jihoon; Kim, Dae Young
- Issue Date
- Apr-2021
- Publisher
- Wiley - VCH Verlag GmbH & Co. KG
- Keywords
- ortho-Quinone methides; 4H-chromenes; photoredox reaction; multicomponent reaction
- Citation
- Asian Journal of Organic Chemistry, v.10, no.4, pp 799 - 802
- Pages
- 4
- Journal Title
- Asian Journal of Organic Chemistry
- Volume
- 10
- Number
- 4
- Start Page
- 799
- End Page
- 802
- ISSN
- 2193-5807
2193-5815
- Abstract
- Visible light-mediated photocatalytic trifluoromethylation, single electron transfer (SET) oxidation, and cycloaddition cascades of 2-vinyl phenols with Umemoto's reagent and malononitrile were developed. This approach provided the multicomponent synthesis of trifluoromethylated 4H-chromenes via the in situ generation of o-quinone methides, followed by sequential cyclization.
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Related Researcher
- Kim, Dae Young
- College of Natural Sciences (Department of Chemistry)