Electrochemical N-Centered Radical Addition/Semipinacol Rearrangement Sequence of Alkenyl Cyclobutanols: Synthesis of beta-Amino Cyclic Ketones
- Authors
- Jang, Jihoon; Kim, Dae Young
- Issue Date
- Dec-2022
- Publisher
- Wiley - VCH Verlag GmbH & Co. KG
- Keywords
- Amination; alkenyl cyclobutanols; beta-amino ketones; electrosynthesis
- Citation
- Asian Journal of Organic Chemistry, v.11, no.12
- Journal Title
- Asian Journal of Organic Chemistry
- Volume
- 11
- Number
- 12
- URI
- https://scholarworks.bwise.kr/sch/handle/2021.sw.sch/21989
- DOI
- 10.1002/ajoc.202200531
- ISSN
- 2193-5807
2193-5815
- Abstract
- The electrochemical N-centered radical addition/semipinacol rearrangement sequence of alkenyl cyclobutanols with sulfonimides is described. This transformation is an environmentally friendly approach that uses cheap and easily handled sulfonimides as N-centered radical sources and successfully avoiding the use of stoichiometric amounts of external redox reagents. The beta-amino cyclic ketone derivatives could be synthesized in moderate to high yields from alkenyl cyclobutanol derivatives under mild constant current electrolysis conditions.
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