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Organocatalytic Enantioselective One-pot Synthesis of Dihydrocoumarins via C-H Oxidation and Cyclization Cascade
- Authors
- Kim, Kyeong Seop; Kim, Dae Young
- Issue Date
- Oct-2023
- Publisher
- WILEY-V C H VERLAG GMBH
- Keywords
- Organocatalysis; One-pot reaction; ortho-Quinone methides; Dihydrocoumarins; Oxazolones
- Citation
- ASIAN JOURNAL OF ORGANIC CHEMISTRY, v.12, no.10
- Journal Title
- ASIAN JOURNAL OF ORGANIC CHEMISTRY
- Volume
- 12
- Number
- 10
- ISSN
- 2193-5807
2193-5815
- Abstract
- Chiral 3,4-dihydrocoumarin derivatives were obtained from 2-benzyl phenols and oxazolones in moderate to high yields with excellent enantioselectivitie (up to 96 % ee) through one-pot cascade via C-H oxidation and cyclization cascade using a binaphthyl-modified squaramide bifunctional organocatalyst under mild reaction conditions.
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Related Researcher
- Kim, Dae Young
- College of Natural Sciences (Department of Chemistry)