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Visible light-mediated photocatalytic phosphorylation of vinyl azides: A mild synthesis of beta-ketophosphine oxides

Authors
Jung, Hye ImKim, Dae Young
Issue Date
1-Feb-2020
Publisher
Marcel Dekker Inc.
Keywords
beta-ketophosphine oxides; photoredox reaction; radical process; vinyl azides
Citation
Synthetic Communications, v.50, no.3, pp 380 - 387
Pages
8
Journal Title
Synthetic Communications
Volume
50
Number
3
Start Page
380
End Page
387
URI
https://scholarworks.bwise.kr/sch/handle/2021.sw.sch/3109
DOI
10.1080/00397911.2019.1696364
ISSN
0039-7911
1532-2432
Abstract
The photoredox-catalyzed phosphorylation of vinyl azides is described in this paper. The reaction proceeded smoothly using an inexpensive and easily-accessible Eosin Y as a photocatalyst under mild reaction conditions without any other oxidant, metal, or additive. This synthetic method affords a convenient way to prepare beta-ketophosphine oxides.
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