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Electrochemical oxidative selenylation of imidazo[1,2-a]pyridines with diselenides

Authors
Kim, Yeon JooKim, Dae Young
Issue Date
7-Mar-2019
Publisher
Elsevier BV
Keywords
Selenylation; Electrochemical oxidation; Imidazo[1,2-a]pyridines; 3-Selenylated imidazopyridines
Citation
Tetrahedron Letters, v.60, no.10, pp 739 - 742
Pages
4
Journal Title
Tetrahedron Letters
Volume
60
Number
10
Start Page
739
End Page
742
URI
https://scholarworks.bwise.kr/sch/handle/2021.sw.sch/4656
DOI
10.1016/j.tetlet.2019.02.001
ISSN
0040-4039
Abstract
Electrochemical oxidative selenylation of imidazo[1,2-a]pyridines has been developed. The reaction proceeds in an undivided electrochemical cell equipped with glassy carbon electrodes employing LiClO4 as a supporting electrolyte. This approach is environmentally benign by using shelf-stable diselenides as selenium source and electrons as oxidizing reagents. The present protocol offers a facile way to prepare 3-selenylated imidazopyridine derivatives. (C) 2019 Elsevier Ltd. All rights reserved.
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