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Synthesis of Ring-Fused 1-Benzazepines via [1,5]-Hydride Shift/7-Endo Cyclization Sequences
- Authors
- Suh, Chang Won; Kwon, Su Jin; Kim, Dae Young
- Issue Date
- 17-Mar-2017
- Publisher
- American Chemical Society
- Keywords
- Ring-Fused 1‑Benzazepines; [1; 5]-Hydride Shift/7-Endo Cyclization Sequences; Redox reaction
- Citation
- Organic Letters, v.19, no.6, pp 1334 - 1337
- Pages
- 4
- Journal Title
- Organic Letters
- Volume
- 19
- Number
- 6
- Start Page
- 1334
- End Page
- 1337
- ISSN
- 1523-7060
1523-7052
- Abstract
- Synthesis of 1-benzazepines has been achieved via a [1,5] hydride shift/7-endo cyclization sequence. The focus of this research is a direct transformation of 2-(aryl)cyclopropane 1,1-diester derivatives into 1benzazepines using a cyclopropane moiety as the hydride acceptor in internal redox reactions.
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Related Researcher
- Kim, Dae Young
- College of Natural Sciences (Department of Chemistry)