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Organo- and Organometallic-Catalytic Intramolecular [1,5]-Hydride Transfer/Cyclization Process through C(sp(3))-H Bond Activation
- Authors
- Kwon, Su Jin; Kim, Dae Young
- Issue Date
- Jun-2016
- Publisher
- John Wiley & Sons Inc.
- Keywords
- atom economy; C(sp3)-H activation; [1,5]-hydride transfer; cyclization; organocatalysis; redox chemistry
- Citation
- Chemical Record, v.16, no.3, pp 1191 - 1203
- Pages
- 13
- Journal Title
- Chemical Record
- Volume
- 16
- Number
- 3
- Start Page
- 1191
- End Page
- 1203
- ISSN
- 1527-8999
1528-0691
- Abstract
- The direct functionalization of C(sp(3))-H bonds is one of the most synthetically powerful research areas in current organic synthesis. Organocatalytic C(sp(3))-H bond activation reactions have recently been developed in addition to the traditional metal-catalyzed C(sp(3))-H activation reactions. In this review, we aim to give a brief overview of organo- and organometallic internal redox cascade reactions with respect to the mechanism, the reactivity of hydrogen donors and acceptors, and the migration modes of hydrogen.
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Related Researcher
- Kim, Dae Young
- College of Natural Sciences (Department of Chemistry)