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Organic redox cascade cyclization of 2-alkynylquinones by ascorbic acid in combination with a copper catalyst and its application to formal synthesis of liphagal
- Authors
- Jeong, T[Jeong, Taejoo]; Okanishi, Y[Okanishi, Yusuke]; Yotsui, S[Yotsui, Sora]; Kim, IS[Kim, In Su]; Yoshimitsu, T[Yoshimitsu, Takehiko]
- Issue Date
- 13-Feb-2023
- Publisher
- ROYAL SOC CHEMISTRY
- Citation
- NEW JOURNAL OF CHEMISTRY, v.47, no.7, pp.3425 - 3429
- Indexed
- SCIE
SCOPUS
- Journal Title
- NEW JOURNAL OF CHEMISTRY
- Volume
- 47
- Number
- 7
- Start Page
- 3425
- End Page
- 3429
- ISSN
- 1144-0546
- Abstract
- A stoichiometric amount of ascorbic acid in combination with CuCl2 center dot 2H(2)O catalyst was found to promote the organic redox cascade transformation of alkynylquinones, successfully furnishing hydroxybenzofuran derivatives. By applying the present organic redox-driven copper-catalyzed cyclization protocol, a formal synthetic route to liphagal has been developed.
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Collections - Pharmacy > Department of Pharmacy > 1. Journal Articles
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