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A Discrete Molecule and a 1D Coordination Polymer of Cadmium(II): Preparation, Structures, and Properties of [Cd(L-1)(2)(NO3)(2)(CH3OH)] and {[Cd(L-2)(CH3COO)(2)]center dot(CH3OH)}(infinity) (L-1 = (4-Py)-CH=N-C10H6-NH2; L-2 = (3-Py)-CH=N-C10H6-N=CH-(3-Py))A Discrete Molecule and a 1D Coordination Polymer of Cadmium(II): Preparation, Structures, and Properties of [Cd(L1)2(NO3)2(CH3OH)] and {[Cd(L2)(CH3COO)2]·(CH3OH)}∞ (L1 = (4-Py)?CH=N?C10H6?NH2; L2 = (3-Py)?CH=N?C10H6?N=CH?(3-Py))
- Other Titles
- A Discrete Molecule and a 1D Coordination Polymer of Cadmium(II): Preparation, Structures, and Properties of [Cd(L1)2(NO3)2(CH3OH)] and {[Cd(L2)(CH3COO)2]·(CH3OH)}∞ (L1 = (4-Py)?CH=N?C10H6?NH2; L2 = (3-Py)?CH=N?C10H6?N=CH?(3-Py))
- Issue Date
- Oct-2019
- Publisher
- WILEY-V C H VERLAG GMBH
- Keywords
- Asymmetric ligand; Cadmium coordination polymer; Pyridyl-amine ligand; Amine group
- Citation
- BULLETIN OF THE KOREAN CHEMICAL SOCIETY, v.40, no.10, pp.958 - 962
- Indexed
- SCIE
SCOPUS
KCI
- Journal Title
- BULLETIN OF THE KOREAN CHEMICAL SOCIETY
- Volume
- 40
- Number
- 10
- Start Page
- 958
- End Page
- 962
- ISSN
- 1229-5949
- Abstract
- An asymmetric ligand, (4-py)-CH=N-C10H6-NH2 (L-1), was prepared from 4-pyridinecarboxaldehyde and 1,5-diaminonaphthalene. The ligand L-1 reacted with Cd(NO3)(2)center dot 4H(2)O in methanol to give a discrete molecular complex, [Cd(L-1)(2)(NO3)(2)(CH3OH)] (1). In addition, a 1D cadmium coordination polymer possessing a methanol molecule, {[Cd(L-2)(CH3COO)(2)]center dot(CH3OH)}(infinity) (2), was prepared from a symmetric ligand (L-2 = (3-py)-CH=N-C10H6-N=CH-(3-py)) and Cd(OAc)(2)center dot 2H(2)O.
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