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Effects of Sulfurization Pressure on the Conversion Efficiency of Cosputtered Cu2ZnSnS4 Thin Film Solar Cellsopen access

Authors
Khalkar, A[Khalkar, Arun]Lim, KS[Lim, Kwang-Soo]Yu, SM[Yu, Seong-Man]Shin, DW[Shin, Dong-Wook]Oh, TS[Oh, Tae-Sik]Yoo, JB[Yoo, Ji-Beom]
Issue Date
2015
Publisher
HINDAWI PUBLISHING CORP
Citation
INTERNATIONAL JOURNAL OF PHOTOENERGY
Indexed
SCIE
SCOPUS
Journal Title
INTERNATIONAL JOURNAL OF PHOTOENERGY
URI
https://scholarworks.bwise.kr/skku/handle/2021.sw.skku/49316
DOI
10.1155/2015/750846
ISSN
1110-662X
Abstract
We report herein Cu2ZnSnS4 (CZTS) thin film solar cells with 6.75% conversion efficiency, without an antireflection coating. The CZTS precursors have been prepared by cosputtering using three different targets on Mo-coated substrates: copper (Cu), tin sulfide (SnS), and zinc (Zn). The postsulfurization was carried out at different pressures in a H2S/N-2 environment at 550 degrees C for one hour. A comparative study on the performances of solar cells with CZTS absorber layers prepared at different sulfurization pressures was carried out. The device efficiency of 1.67% using CZTS absorber and low pressure sulfurization is drastically improved, to an efficiency of 6.75% with atmospheric pressure sulfurization.
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