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New heteroleptic magnesium complexes for MgO thin film application
- Authors
- Kim, HS[Kim, Hyo-Suk]; George, SM[George, Sheby Mary]; Park, BK[Park, Bo Keun]; Son, SU[Son, Seung Uk]; Kim, CG[Kim, Chang Gyoun]; Chung, TM[Chung, Taek-Mo]
- Issue Date
- 2015
- Publisher
- ROYAL SOC CHEMISTRY
- Citation
- DALTON TRANSACTIONS, v.44, no.5, pp.2103 - 2109
- Indexed
- SCIE
SCOPUS
- Journal Title
- DALTON TRANSACTIONS
- Volume
- 44
- Number
- 5
- Start Page
- 2103
- End Page
- 2109
- ISSN
- 1477-9226
- Abstract
- Novel heteroleptic magnesium complexes, [Mg(dmamp)(acac)](2) (1), [Mg(dmamp)(tmhd)](2) (2), [ Mg(dmamp)( tfac)](2) (3), and [ Mg(dmamp)(hfac)](2) (4), were successfully synthesized using dmamp and beta-diketonate as ligands. The thermogravimetric analyses and volatile studies of the complexes showed that the complexes 2 and 4 display high volatility and thermal stability. The single crystal X-ray study of the complexes reveals that both the complexes 1 and 2 were crystalized in the triclinic space group and as dimers, where magnesium atoms are in the pentacoordinate state with distorted trigonal bipyramidal geometry.
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