Direct Hydrogenation of Biomass-Derived Butyric Acid to n-Butanol over a Ruthenium-Tin Bimetallic Catalyst
- Authors
- Lee, JM[Lee, Jong-Min]; Upare, PP[Upare, Pravin P.]; Chang, JS[Chang, Jong-San]; Hwang, YK[Hwang, Young Kyu]; Lee, JH[Lee, Jeong Ho]; Hwang, DW[Hwang, Dong Won]; Hong, DY[Hong, Do-Young]; Lee, SH[Lee, Seung Hwan]; Jeong, MG[Jeong, Myung-Geun]; Kim, YD[Kim, Young Dok]; Kwon, YU[Kwon, Young-Uk]
- Issue Date
- Nov-2014
- Publisher
- WILEY-V C H VERLAG GMBH
- Keywords
- alcohols; biomass; carboxylic acids; hydrogenation; ruthenium
- Citation
- CHEMSUSCHEM, v.7, no.11, pp.2998 - 3001
- Indexed
- SCIE
SCOPUS
- Journal Title
- CHEMSUSCHEM
- Volume
- 7
- Number
- 11
- Start Page
- 2998
- End Page
- 3001
- URI
- https://scholarworks.bwise.kr/skku/handle/2021.sw.skku/51059
- DOI
- 10.1002/cssc.201402311
- ISSN
- 1864-5631
- Abstract
- Catalytic hydrogenation of organic carboxylic acids and their esters, for example, cellulosic ethanol from fermentation of acetic acid and hydrogenation of ethyl acetate is a promising possibility for future biorefinery concepts. A hybrid conversion process based on selective hydrogenation of butyric acid combined with fermentation of glucose has been developed for producing biobutanol. ZnO-supported Ru-Sn bimetallic catalysts exhibits unprecedentedly superior performance in the vapor-phase hydrogenation of biomass-derived butyric acid to n-butanol (>98% yield) for 3500h without deactivation.
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Collections - Science > Department of Chemistry > 1. Journal Articles
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