Luminescence and structural properties of self-assembled Y(V,P)O-4:Eu3+@amorphous-K-VO3 core/shell nanophosphors
- Authors
- Jo, DS[Jo, Deok Su]; Senthil, K[Senthil, Karuppanan]; Takaki, M[Takaki, Masaki]; Yoon, DH[Yoon, Dae Ho]
- Issue Date
- Jun-2013
- Publisher
- CERAMIC SOC JAPAN-NIPPON SERAMIKKUSU KYOKAI
- Keywords
- Nanophosphors; Nanoparticle; Surface treatment; Core/shell
- Citation
- JOURNAL OF THE CERAMIC SOCIETY OF JAPAN, v.121, no.1414, pp.487 - 493
- Indexed
- SCIE
- Journal Title
- JOURNAL OF THE CERAMIC SOCIETY OF JAPAN
- Volume
- 121
- Number
- 1414
- Start Page
- 487
- End Page
- 493
- URI
- https://scholarworks.bwise.kr/skku/handle/2021.sw.skku/60505
- ISSN
- 1882-0743
- Abstract
- A Liquid-Phase Precursor method followed by a 5% KOH solution treatment was employed for the facile synthesis of Y(V,P)O-4:Eu3+@amorphous-K-VO3 core/shell nanophosphors with non-stoichiometric composition Y-x(V0.44P0.56)O-4:Eu-0.1 (x = 0.855, 0.875, 0.90 and 0.965). It was observed that this non-stoichiometric composition approach leads to the control of the size, shape and unit cell parameters depending upon the Y concentration. The shell layer of 2-7 nm formed by alkaline solution treatment at room-temperature was observed by Transmission Electron Microscope (TEM). The particle size grew up by 20-50 nm and the luminescence properties were enhanced by 9-31% after the KOH solution treatment. In contrast, the micro-sized Y(V,P)O-4:Eu3+ phosphors treated by the KOH solution did not show any change in their luminescence properties. This KOH solution treatment opens new possibilities to facilely synthesize Y(V,P)O-4:Eu3+@amorphous-K-VO3 core/shell nanophosphors with highly stable properties and improved luminescence. (C) 2013 The Ceramic Society of Japan. All rights reserved.
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Collections - Engineering > School of Advanced Materials Science and Engineering > 1. Journal Articles
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