Synthesis and luminescent characteristics of Ca2-xSrxSiO4:Eu2+ as a potential green-emitting phosphor for near UV-white LED applications
- Authors
- Park, WJ[Park, W. J.]; Song, YH[Song, Y. H.]; Yoon, DH[Yoon, D. H.]
- Issue Date
- 15-Oct-2010
- Publisher
- ELSEVIER SCIENCE BV
- Keywords
- Green-emitting phosphor; White LEDs; Silicate composition; Concentration quenching
- Citation
- MATERIALS SCIENCE AND ENGINEERING B-ADVANCED FUNCTIONAL SOLID-STATE MATERIALS, v.173, no.1-3, pp.76 - 79
- Indexed
- SCIE
SCOPUS
- Journal Title
- MATERIALS SCIENCE AND ENGINEERING B-ADVANCED FUNCTIONAL SOLID-STATE MATERIALS
- Volume
- 173
- Number
- 1-3
- Start Page
- 76
- End Page
- 79
- URI
- https://scholarworks.bwise.kr/skku/handle/2021.sw.skku/73085
- DOI
- 10.1016/j.mseb.2010.01.041
- ISSN
- 0921-5107
- Abstract
- The photoluminescence properties of enhanced green-emitting Ca2-xSrxSiO4:Eu2+ were optimized for applications to near ultraviolet light emitting diodes (LEDs). The optimal firing conditions for Ca2-xSrxSiO4:Eu2+ prepared by solid-state reaction synthesis were found to be 1300 degrees C for 6 h. Ca2-xSrxSiO4:Eu2+ showed strong green emission peak at approximately 520 nm under excitation by near UV light of 390 nm. The effects of Sr2+ substitution into the Ca2+ sites on the emission band shift were investigated. The enhanced emission intensity and blue shift in the emission band of Ca2-xSrxSiO4:Eu2+ was explained by competition between crystal field and nephelauxetic effect. These characteristics make Ca2-xSrxSiO4:Eu2+ a good candidate for green-emitting phosphors in the production of white light in phosphor conversion white LEDs. (C) 2010 Elsevier B.V. All rights reserved.
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Collections - Engineering > School of Advanced Materials Science and Engineering > 1. Journal Articles
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