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Synthesis and luminescent characteristics of Ca2-xSrxSiO4:Eu2+ as a potential green-emitting phosphor for near UV-white LED applications

Authors
Park, WJ[Park, W. J.]Song, YH[Song, Y. H.]Yoon, DH[Yoon, D. H.]
Issue Date
15-Oct-2010
Publisher
ELSEVIER SCIENCE BV
Keywords
Green-emitting phosphor; White LEDs; Silicate composition; Concentration quenching
Citation
MATERIALS SCIENCE AND ENGINEERING B-ADVANCED FUNCTIONAL SOLID-STATE MATERIALS, v.173, no.1-3, pp.76 - 79
Indexed
SCIE
SCOPUS
Journal Title
MATERIALS SCIENCE AND ENGINEERING B-ADVANCED FUNCTIONAL SOLID-STATE MATERIALS
Volume
173
Number
1-3
Start Page
76
End Page
79
URI
https://scholarworks.bwise.kr/skku/handle/2021.sw.skku/73085
DOI
10.1016/j.mseb.2010.01.041
ISSN
0921-5107
Abstract
The photoluminescence properties of enhanced green-emitting Ca2-xSrxSiO4:Eu2+ were optimized for applications to near ultraviolet light emitting diodes (LEDs). The optimal firing conditions for Ca2-xSrxSiO4:Eu2+ prepared by solid-state reaction synthesis were found to be 1300 degrees C for 6 h. Ca2-xSrxSiO4:Eu2+ showed strong green emission peak at approximately 520 nm under excitation by near UV light of 390 nm. The effects of Sr2+ substitution into the Ca2+ sites on the emission band shift were investigated. The enhanced emission intensity and blue shift in the emission band of Ca2-xSrxSiO4:Eu2+ was explained by competition between crystal field and nephelauxetic effect. These characteristics make Ca2-xSrxSiO4:Eu2+ a good candidate for green-emitting phosphors in the production of white light in phosphor conversion white LEDs. (C) 2010 Elsevier B.V. All rights reserved.
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