Two Novel 3-D Zinc Compounds with Mixture Ligands of H3BTB and 4,4 '-Bipy: Crystal Structures, Blue Fluorescence and Single Point Energy Calculation
- Authors
- Zhang, XC[Zhang, Xiu-Cheng]; Xu, L[Xu, Ling]; Liu, WG[Liu, Wen-Guang]; Liu, B[Liu, Bing]
- Issue Date
- 20-Sep-2010
- Publisher
- KOREAN CHEMICAL SOC
- Keywords
- 1,2,3-Benzenetricarboxylic acid; Crystal structure; Fluorescence; Single point energy calculation
- Citation
- BULLETIN OF THE KOREAN CHEMICAL SOCIETY, v.31, no.9, pp.2598 - 2602
- Indexed
- SCIE
SCOPUS
KCI
- Journal Title
- BULLETIN OF THE KOREAN CHEMICAL SOCIETY
- Volume
- 31
- Number
- 9
- Start Page
- 2598
- End Page
- 2602
- URI
- https://scholarworks.bwise.kr/skku/handle/2021.sw.skku/73302
- DOI
- 10.5012/bkcs.2010.31.9.2598
- ISSN
- 0253-2964
- Abstract
- Two 3-D zinc framework compounds, [Zn-6(BTB)(4)(4,4'-bipy)(4)(H2O)(4)]center dot 9H(2)O (1) and [Zn-3(BTB)(2)(4,4'-bipy)(2)(H2O)(2)]center dot 5H(2)O (2) (H3BTB = 1,2,3-benzenetricarboxylic acid, 4,4'-bipy = 4,4'-bipyridine), are obtained from the diffusion method and hydrothermal reaction respectively. Though 1 and 2 has the same coordination geometries of zinc atoms and coordination mode of BTB3-, their 2-D layers are different: mirror symmetric layers in 1; parallel ones in 2, further connecting by 4,4'-bipy into 3-D frameworks. The hydrothermal reaction of 2 results in a more stable 3-D framework than the one in 1, which is supported by the single point energy calculations. 1 and 2 show similar blue fluorescence at 417 nm, which can be assigned to LMCT.
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