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Growth of Metal-Free Carbon Nanotubes with an Amorphous Carbon Catalyst Layer

Authors
Song, W[Song, Woochang]Lim, DG[Lim, Dong-Gun]Kim, HD[Kim, Hee Dong]Lee, JH[Lee, Jae-Hyeoung]Cha, J[Cha, Jaesang]Park, G[Park, Gooman]Choi, EC[Choi, Eun Chang]Hwang, HS[Hwang, Hyun Suk]Cho, HJ[Cho, Hyung Jun]Hong, B[Hong, Byungyou]Choi, WS[Choi, Won Seok]
Issue Date
Oct-2008
Publisher
KOREAN PHYSICAL SOC
Citation
JOURNAL OF THE KOREAN PHYSICAL SOCIETY, v.53, no.4, pp.2142 - 2146
Indexed
SCIE
SCOPUS
KCI
Journal Title
JOURNAL OF THE KOREAN PHYSICAL SOCIETY
Volume
53
Number
4
Start Page
2142
End Page
2146
URI
https://scholarworks.bwise.kr/skku/handle/2021.sw.skku/80493
ISSN
0374-4884
Abstract
An amorphous carbon (a-C) thin film was used as a catalyst, layer to grow metal-free carbon nanotubes (CNTs). The a-C films were deposited with a closed-field unbalanced magnetron (CFUBM) sputtering method on Si substrates. The CNTs were prepared using a microwave plasma-enhanced chemical-vapor deposition (MPECVD) method with an a-C catalyst film coated onto a silicon substrate by using methane (CH4) and hydrogen (H-2) gas. The CNTs were grown at different temperatures (550 degrees C, 650 degrees C and 750 degrees C) with other conditions being held constant. Field emission scanning electron microscopy (FE-SEM) images showed growth trend of the CNTs against temperature. High-resolution transmission electron microscopy (HR-TEM) images showed the CNTs to be multi-walled. Energy dispersive spectroscopy (EDS) measurements confirmed that the CNTs consisted solely of carbon.
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