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Effects of additive C4F8 during inductively coupled BCl3/C4F8/Ar plasma etching of TaN and HfO2 for gate stack patterning

Authors
Ko, JH[Ko, J. H.]Kim, DY[Kim, D. Y.]Park, MS[Park, M. S.]Lee, NE[Lee, N.-E.]Lee, SS[Lee, S. S.]Ahn, J[Ahn, Jinho]Mok, H[Mok, Hyungsoo]
Issue Date
Jul-2007
Publisher
A V S AMER INST PHYSICS
Citation
JOURNAL OF VACUUM SCIENCE & TECHNOLOGY A, v.25, no.4, pp.990 - 995
Indexed
SCIE
SCOPUS
Journal Title
JOURNAL OF VACUUM SCIENCE & TECHNOLOGY A
Volume
25
Number
4
Start Page
990
End Page
995
URI
https://scholarworks.bwise.kr/skku/handle/2021.sw.skku/84211
DOI
10.1116/1.2747621
ISSN
0734-2101
Abstract
In this work, the authors investigated the etching characteristics of TaN and HfO2 layers for gate stack patterning in BCl3/Ar and BCl3/C4F8/Ar inductively coupled plasmas and the effects of C4F8 addition on the etch selectivity of the TaN to the HfO2 layer. Addition of C4F8 gas to the BCl3/Ar chemistry improved the TaN/HfO2 etch selectivity because adding the C4F8 gas enhances the formation of the CFxCly passivation layer on HfO2 surface and decreased the HfO2 etch rate more rapidly than the TaN etch rate in a disproportionate way. Reduction in the etch time for HfO2 layer also increases the TaN/HfO2 etch selectivity because the etch time gets closer to the initiation time for HfO2 etching. (c) 2007 American Vacuum Society.
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